Gamestop have listed a Wii GoldenEye controller in their pre-order list, priced at $69.99.
Though the price seems very high, it is very likely that this is actually a bundle that comes with the game and the gun, which makes the price much more reasonable.
There are also two possibilities of what it looks like, one of which is just the original Nintendo Classic controller with a gold finish, while the other is the Wii Zapper style controller.
The new GoldenEye will support all possible controllers for the Wii (including the GameCube controller).