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Scorpion 
Scorpion aka Mac Gargan was the subject of J.Jonah Jameson’s stupidity. Jameson decided to pay $10,000 to Gargan to be the subject of an experiment. The experiment, created by Dr. Farley Stillwell, endowed the subject with the characteristic of another animal. Unfortunately the process resulted in the loss of Gargan’s sanity, and the creation of the super-powered criminal menace known as the Scorpion. With his mechanical tail, speed, and strength, Scorpion was always been more than a match for Spider-Man.
